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Friday, December 28, 2018

Mlk Nobel Peace Prize Speech Analysis

Elizabeth Potoae Ms. Casberg AP English P. 3 15 January 2012 AP Essay MLK jr. Martin Luther poof Jr. has always been a cracking public speaker because of the amount of displeasure instilled in his words and his extreme controller in putting images in the minds of his earshot. non to mention, his message is explicitly conveyed to the audience. Martin Luther King Jr. establishes his acceptance of the Nobel Peace Prize with regnant insight of the Civil Rights Movement, and the must to traverse segregation through the use of analogical language and repetition/example/ symmetry/ vision to show that our battle with racialism has yet to be over.Martin Luther King uses figurative language to emphasize the importance of the gist behind his words. He says in his reference over and over I am mindful that sole(prenominal) yesterday to render that racism and discrimination is still passing game on. He discusses the struggles and conflicts blacks faced due to the curse and violen ce that is occurring in the world. King repeats the wickedness of the modern situations to allow his audience to reckon that something still needs to be done.He feels, maybe if he says it enough times, mass go out actually do something most it, because the award he is receiving simply means nonhing without action. To show that he will not founder up until a change comes, he repeats the words I refuse to accept and goes on to identify of the excuses people use as wherefore not to change. Martin Luther King Jr. believes that action will lead us cut down a road where love and accept await. Here we can find a world of freedom and justice.Martin Luther King uses imagery with his figurative language. He uses it to not only tell exclusively show his audiences how the current ways of people are not helping pave the way to a brighter future day, which encompasses no discrimination, only peace. He compares racism to a starless night to expatiate that racism is a dark and in l oyalty inhumane part in the lives of legion(predicate) people. He says beauty is rightfulness and truth beauty to depict in the minds of audience that once theyve acknowledged that the truth is the truth in the ircumstances they face, it will be a much more beautiful tomorrow than they could ever imagine. Martin Luther King wants everyone to honestly hypothecate about the conflict we have and steady down whether we want to take part of the ascendent or add to the problem when he says this faith can give us courage to face the uncertainties of the future and give us new strength to live forward. And by doing so, people will graze and build a better future for all of us, where there is no racism, but peace.

Wednesday, December 26, 2018

'Health Complications Caused by Chlamydia in Males\r'

'The topic I postulate elect to tie beam it with is Chlamydia n individuals aged 16-25. I am going to see whether the wellness advance is used as a brass of empowerment or a system of program line. Main body Chlamydia place cause many complications in males and females, a few examples of these argon; abdominal pain, pelvic pain, inability to wee pregnant, potenti solelyy deleterious octopi pregnancy, swelling in one/ some(prenominal) testicles, fever and close outing a man from universe able to father children states Brown, N (2013).The brass ar setting up ship canal to prevent this by setting up forego Chlamydia wake to Individuals aged 0-25, this Is empowerment. By the government doing this It Is making Individuals chance upon precautions and take in regular checks. It excessively makes individuals respect themselves as when they know what Chlamydia can do to them they whitethorn as well vary using condoms to get the statistics of battalion contracting Chlam ydia.It can as well as be seen as get a lineing to pass water for individuals as they be pushing/persuading them to use contraception and keep getting themselves analyse bring fall out after a impertinent sexual partner, this Is because If individuals start becoming cognizant and checking themselves, and similarly using breastplate It forget reduce the amount of money the INS are spending on treatment, (1 tablet or a weeks worth of antibiotics). The individuals that dont use protection or get checked out regularly could be having sexual relationships with others in the community and passing on the transmission system.This is why when individuals find out they oblige the contagion they are advised to tell their onetime(prenominal) and current partners to get checked out as well. The antibiotics that are prescribed are the medical approach as It alms to prevent disease. This topic also links to port hang as it encourages individuals to adapt reasoning(a) behaviors, it is also a form of wellness education as the individuals are schooling about Chlamydia also it is un presumable to be successful unless the individual is ready to sate action.For example if an individual is not involuntary to use protection and/or get regular tests then there is not a lot that can be done, unless they decide to change their ways and try help themselves. The education approach also links to this as It alms to provide cognition influence relating to Chlamydia as it aims to help individuals pull in the skills and inference to take greater control over their own wellness. For example if you are terrified of what your partner may order when you mention ‘protection you are less likely to mention it, also if you are afraid of the result you may get from the screening tests you may decide not to take one.Social change also has a link to Chlamydia as it aims to make the wellnessy pickaxe the easy choice, some individuals may be too scared to get help, take tes ts or mention anything. This is where individuals need to start making the right choice. The media is an influence on Chlamydia as it encourages individuals viewing it to stay safe, opine after yourselves and others so you dont pass the infection around the community. The government are also an influence on Chlamydia as it is give thanks to them that 16-25 year olds can gain excess Chlamydia screening in clinics INS choices (2011).The critical ground for health promotion is as follows, health promotion is the process of enabling large number to increase control over, and to improve; health of people, communities and populations says Reuters, T (2013). It moves beyond a counsel on individual behavior towards a wide range of complaisant and environmental interventions. Interventions to help change behaviors and environments in ways that are conductive to health. The main goals of health promotion are to reduce health risks and optimize health and productively date lowering tot al health-related costs.At its best, worksheet health promotion creates a culture that fosters vitality, motivation and overall effectiveness of human capital says (Erickson,2006). The subprogram and relevance of health promotion is in tackling the determinants of health, elate promotion will admit combinations of the strategies namely developing personal skills, fortify community action, and creating supportive environments for health, backed by thinking(a) public policy.wellness promotion is a powerfully relevant strategy for social development, in particular as an in-chief(postnominal) set of strategies to address the factors influencing inequalities in health. Health promotion also brings together all the principles that underlie a series of strategies that seek to support conditions that allow populations to be healthy and to make lately choices. The range of strategies draws upon behavioural sciences, public health, education and communication, to name a few, and their respective methodologies says health promotion deputation (2009).Empowerment or control Within this analyze I hurl stated both ways in which it is empowerment and control. and both have equal entitlement; I am swayed to say I in person think that the health promotion is to a greater extent a system of empowerment. This is because the government are setting up schemes that are free for individuals aged 16-25 to access. This shows he empowerment that is presumptuousness to individuals to look after themselves without a cost. too condoms are given for free at the clinic where the Chlamydia screening is taken states (Scholar, Abraham, Kook and Gilmore, 2004).This is empowering people to take precautions so that they dont contract the infection. other point is the media what can happen if they have the infection and dont get checked out. windup Throughout this essay I have shown how health promotion can be used as a system of empowerment and a system of control. I have linked it together with my chosen epic; I have also linked health promotion inside my topic to the different approaches that I have learnt about within my lectures.\r\n'

Sunday, December 23, 2018

'Freedom: Political Philosophy and Populous Positive Liberty Essay\r'

'Freedom remains the repair basis for Ameri tramp society as we know it. Without exemption the great rural area of America would contribute never been founded. To pull in the true teachings of opendom, virtuoso essential consider the scope of the word. Philosophical freedom encompasses the strength to make choices without restraints, while political freedom is the state of being free or else than in physical confinement. Despite the importance of these ideas to our founding fathers, freedom has lost practically of its importance in modern American society. The failure to stress the importance of freedom has diminished the smell of life for the entire American populous.\r\nPositive closeness is the freedom for one to pose all one can (Postive autonomy). This idea can be considered, in general, a totalitarian article of faith because leaders following this ideology much believs it is in spite of appearance their realm to force the citizens to become all they can b e. But this could in like mood be considered democratic by dint of with(predicate) political programs such as welfare, affirmative action, and umpteen former(a)s created to better society. Yet negative conversancy, is the ancient one we want in our lives. so far negative liberty is the freedom from the constraints that keep back us (Negative Liberty).\r\nIn sharp bloodline to the totalitarian principles of positive liberty, negative liberty is based more on libertarian principles in which the regimen takes the backseat allowing people to thrive through their bear actions. A real ball view of this would be the Conservative principle of laissez-faire, an idea that the government should stay a guidance from enacting laws that limit buisness. Liberty constitutes a gnomish principle in the immense ideals of American freedom. Even though Positive liberty seems like a negative involvement when combined with the ideals of Negative liberty a prosperus society can be created. \r\nTo interpret the importance of freedom in American society, we must go back to the rootage: the Declaration of Independence. Jefferson framed the institution roughly the concepts mystify forth by fanny Locke, the father of liberty. The Declaration of Independence created a way to free ourselves from the in exactlyices done upon us by the English monarchy. This document set forth the basis of what a government can reasonably do to value and tax its citizens, before being beyond the appropriate scope of its advocator.\r\nWhen the government exceeds this position one must consider this an usurpation on freedom. This governmental basis becomes extenuated in the broadside of Rights, the foundation of the US constitution. The charge of Rights remains the true source of our freedoms as American. These freedoms include speech, religion etc. These freedoms were â€Å"to be held dear” by all peniss of our society. As a result off the plasticity of these amendments, the American elitists can interpret these for their own ideas.\r\nSince the beginning of America, Elitists wear found a way to hinder the lower and nitty-gritty classes involvement in government through the enormous amount of money human beingdatory to create a successful choice campaign. Taking on an elective theatrical role in government is supposed to be a freedom every member of society can achieve, but with the financial importance of campaigning it is not possible. In the 2004 election campagins alone, canidates spent $144 one million million million dollars out of their own pocket. (’04 Elections Expected to equal Nearly $4 Billion) As displayed by the scrub family, these elitists continue their stronghold on American government.\r\nIf the lower to middle classes can’t find a way to break the barriers that bar them from governmental participation, their prime(a) of life ordain remain vastly behind that of the elitist. To break these barriers the citizen s must rectify to using the principles guaranteed to them through both the Bill of Rights and the Declaration of Independence. Positive Liberty allows us as citizens to bring ourselves to become the beaver we can, which destroys class barriers completley. While Negative Liberty allows us to in whatsoever manner possible liberate ourselves from this lack of freedom.\r\n wizard day in regards to a authority like ours, Jefferson said â€Å"Experience hath shewn, that nonetheless under the best forms of government those entrusted with power have, in time, and by slow operations, pervert it into tyranny” (Thomas Jefferson Quotes). In high rank offices, lower and middle class elected officials would be able to take stands to cheer their peers, not the big buisnesses that are being protected now. This â€Å"ruling class” has in any case enacted laws that protect completely their interest. In 2001 the scrubbing administartion created a pakage to eliminate the estate tax, which applies scarcely to the richest 2% of Americans (Estate Tax loss will punch whole in Budget).\r\n through with(predicate) this idea most of the capital have by these millionaires is never taxed. How fair is that? as well the upper class leaders have taken stands to protect big buisness, allowing them to consecrate subsidaries in tax havens around the gentlemans gentleman preventing most of their income from being taxed. Even though this idea allows the economy to flourish, the rural areaal debt continues to spring for the good of these elites. Throughout the course this soil has taken, the freedom we hold the dearest †the origin Amendment †has been limited through some congressional and executive rulings.\r\nNot except have governmental rulings limited these sounds but in like manner the members of the â€Å"ruling class” underwrite over media and other sources of information. Most media outlets our controlled by wealthy people, who greatly support the elitists running for higher rank ruling offices, oft donating to their campaigns (Who owns CNN? or MSNBC? rudiment? ). Without the ability for someone international this give fraternity to own a prestigious news outlet, propaganda is easily spread without any notice by the people. Not only when has our ability to gain any media control diminished, but also are right to freedom of speech has diminished.\r\nThe people within the nation that is considered the most free and democratic, often find themselves facing oppression when they enterprise to speak against the injustices committed by their government. In one situation a man refused to go to the specified â€Å"protest zones” designated by the Secret Service, often miles off the fashion of the presidential motorcade, he was then supercharged with disorderly conduct (Free Speech Zone). How free is that? This oppression must be rolling off by the people in an attempt to right our sinking nation. Tapping calls for natural law or governmental purposes often requires just cause, but who needs that nowadays.\r\nPresident Bush thrust off any judicial oversight required to tap phone lines and served as the catalyst behind many unnecessary and illegal phone taps. As we take a stand against the abuses by the government against freedom as citizens, we must remain in our boundaries to provide ourselves the superlative opportunity to garner support throughout not only the area, but the nation. If we push our views too radically, our chance to improve our quality of life will fail. Pursing freedom outside the scope outlined in the constitution creates almost an anarchy, which often does not add-on the quality of life but lowers it greatly.\r\nThe passage of arms for freedom within America has taken a turn for the worst as can be seen through this jiffy amount of examples provided. Elitists continue to rule the nation uncontended by anybody. The exponential rate at which our freedoms are being not only diminished but taken off can only be stop through the political activism of everyone involved in this great community. Even though as a single person, we appear weensy in the grand scheme of things, it only takes one person to start volatile reforms..\r\n'

Friday, December 21, 2018

'Preparation of Identification by Ir and Nmr Spectroscopy Essay\r'

'The respondive venomous chloride mickle wherefore be treated with a primary or secondary aminoalkane to give the amide along with HCl, which reacts with the bare amine to give an alkylammonium chloride salt. The mechanism of this process is shown on the following page in scheme 22: [pic] Scheme 2 To withstand out this reception, the machine shown in encounter 1 will be assembled. The utensil must be dry, since thionyl chloride will react with pee to give sulfur dioxide and henry chloride.\r\nThe dosage chloride will past be cooled to room temperature and dissolved in anhydrous divinyl ether. Ice-cold di ethyl radicalamine will be added as a origin in anhydrous ether to form the amide. The resulting ether salmagundi will washed with aqueous atomic number 11 hydroxide (to remove any excess pane of glass chloride), then washed with hydrochloric acid (to remove any excess diethylamine).\r\nThe resulting ether solution of DEET will be desiccated and evaporated to yiel d the crude wareion, which will then be purified by column chromatography to move over arrant(a) DEET. The percent yield from m-toluic acid will be determined and the product will be analyzed by transmission infrared spectroscopy (IR) as a neat sample utilise NaCl plates5 to confirm its structure by (1) look at the major absorptions and comparing them to a correlation table6 and (2) by comparing the spectrum to that of an authorized sample.\r\nThionyl chloride is toxic and corrosive! Do non breath the vapors! Use in a hood! When heating a reaction apparatus, be legitimate that it is dedicate to the air so that pressure cast up and subsequent rupture of the apparatus does not occur. When heating liquids, imbibe sure the liquid is affected (or a boiling chip is added) to prevent â€Å"bumping”. When performing an extraction, make sure to vent the separatory move a good deal to prevent pressure build-up. The apparatus shown in Figure 1 was assembled.\r\nThe 10-mL reaction flask was charged with 0. 275 g of m-toluic acid (0. 0020 mol) and 0. 30 mL of thionyl chloride (0. 492 g, 0. 0041 mol). The condenser water was started, and the mixture was gently heated with stirring on an aluminum block (block temp ~ 90 oC) until boiling started. The reaction mixture was then gently boiled for about 15 minutes. subsequently the boiling period was finished, the reaction mixture was cooled to room temperature. 4. 0 mL of anhydrous ether were added, and the mixture was ablaze at room temperature until a undiversified mixture was obtained. To this solution was added (dropwise over a 15 minute period) a solution of 0. 6 mL of cold (0 oC) diethylamine (0. 462 g, 0. 0063 mol) in 1. 33 mL of anhydrous ether. During the addition, a thick white cloud of diethylamine hydrochloride was formed.\r\nAfter complete addition, the reaction mixture was randy at room temperature for about 10 minutes. 10% aqueous sodium hydroxide (2 mL) was then added, and the reactio n mixture was stirred for an additional 15 minutes at room temperature, then poured into a separatory funnel and allowed to separate. The aqueous storey was discarded, and the organic layer was washed with an additional portion of 10% aqueous sodium hydroxide (2 mL), followed by a portion of 10% hydrochloric acid (2 mL).\r\nThe organic layer was washed with water (2 mL), dried (Na2SO4) and evaporated to yield crude N,N-diethyl-m-toluamide as dark brown liquid. The crude product was filtered through a short aluminum oxide column using hexane as the eluent (~ 5 mL). The hexane solution was evaporated to give 0. 340 g of pure N,N-diethyl-m-toluamide as a yellow liquid. chemical reaction of m-toluic acid with thionyl chloride, followed by diethylamine produced 0. 340 g of a yellow liquid the IR spectrum of which unequivocally showed the presence of the amide carbonyl functional meeting at 1633 cm-1. In addition, absorptions due to open-chain C-H (2980 †2880 cm-1), and aromatic C =C (at 1585 cm-1). The IR spectrum is attached to this report.\r\nThese data are unchanging with the structure of N,N-diethyl-m-toluamide (DEET), shown in Figure 2 below: [pic] Figure 2: N,N-Diethyl-m-toluamide (DEET) In addition, the IR of the product closely corresponds with that of an honest sample of N,N-diethyl-m-toluamide (DEET) shown in the lab text. 9 Also, the 1H-NMR shows the presence of four (4) aromatic protons in the region 7. 3 †7. 1 ppm, as well as a terce (3) proton singlet at 2. 35 ppm, which corresponds to the benzylic methyl group. The presence of 2 ethyl groups is clearly shown by the presence of two quartets which comprise to 2 protons each at 3. 53 and 3. 24 ppm, and two triplets which integrate to 3 protons each at 1. 23 and 1. 09 ppm.\r\n'